If the potential energy of a gas molecule is $U = \frac{M}{r^6} - \frac{N}{r^{12}}$,where $M$ and $N$ are positive constants,then the potential energy at equilibrium must be

$A$ fixed thermally conducting cylinder has a radius $R$ and height $L_0$. The cylinder is open at its bottom and has a small hole at its top. $A$ piston of mass $M$ is held at a distance $L$ from the top surface,as shown in the figure. The atmospheric pressure is $P_0$.
$1.$ The piston is now pulled out slowly and held at a distance $2L$ from the top. The pressure in the cylinder between its top and the piston will then be
$(A) P_0$ $(B) \frac{P_0}{2}$ $(C) \frac{P_0}{2} + \frac{Mg}{\pi R^2}$ $(D) \frac{P_0}{2} - \frac{Mg}{\pi R^2}$
$2.$ While the piston is at a distance $2L$ from the top,the hole at the top is sealed. The piston is then released,to a position where it can stay in equilibrium. In this condition,the distance of the piston from the top is
$(A) \left(\frac{2P_0 \pi R^2}{\pi R^2 P_0 + Mg}\right)(2L)$ $(B) \left(\frac{P_0 \pi R^2 - Mg}{\pi R^2 P_0}\right)(2L)$ $(C) \left(\frac{P_0 \pi R^2 + Mg}{\pi R^2 P_0}\right)(2L)$ $(D) \left(\frac{P_0 \pi R^2}{\pi R^2 P_0 - Mg}\right)(2L)$
$3.$ The piston is taken completely out of the cylinder. The hole at the top is sealed. $A$ water tank is brought below the cylinder and put in a position so that the water surface in the tank is at the same level as the top of the cylinder as shown in the figure. The density of the water is $\rho$. In equilibrium,the height $H$ of the water column in the cylinder satisfies
$(A) \rho g(L_0 - H)^2 + P_0(L_0 - H) + L_0 P_0 = 0$
$(B) \rho g(L_0 - H)^2 - P_0(L_0 - H) - L_0 P_0 = 0$
$(C) \rho g(L_0 - H)^2 + P_0(L_0 - H) - L_0 P_0 = 0$
$(D) \rho g(L_0 - H)^2 - P_0(L_0 - H) + L_0 P_0 = 0$
Give the answer for questions $1, 2$ and $3$.

Consider the following statements for air molecules in an air-tight container:
$(I)$ The average speed of molecules is larger than root mean square speed.
$(II)$ Mean free path of molecules is larger than the mean distance between molecules.
$(III)$ Mean free path of molecules increases with temperature.
$(IV)$ The rms speed of nitrogen is smaller than oxygen molecule.
Which of the above statements are correct?

At a temperature of $300 \ K$,the average translational kinetic energy and $rms$ speed of a sample of oxygen gas are $6.21 \times 10^{-21} \ J$ and $484 \ m/s$ respectively. At $600 \ K$,these values will be respectively: (Assume ideal gas behavior)

$A$ closed vessel contains a mixture of two diatomic gases $A$ and $B$. Molar mass of $A$ is $16$ times that of $B$ $(M_A = 16 M_B)$ and mass of gas $A$ contained in the vessel is $2$ times that of $B$ $(m_A = 2 m_B)$. Which of the following statements are true?
$(i)$ Average kinetic energy per molecule of $A$ is equal to that of $B$.
$(ii)$ Root mean square value of translational velocity of $B$ is four times that of $A$.
$(iii)$ Pressure exerted by $B$ is eight times that exerted by $A$.
$(iv)$ Number of molecules of $B$ in the cylinder is eight times that of $A$.

$A$ vessel contains $14\,g$ of nitrogen gas at a temperature of $27^{\circ}\,C$. The amount of heat to be transferred to the gas to double the r.m.s. speed of its molecules will be $......J$ (Take $R = 8.32\,J\,mol^{-1}K^{-1}$)